Organic Chemistry

Download Alternative Solvents for Green Chemistry (RSC Green by Francesca M. Kerton PDF

By Francesca M. Kerton

Conventional solvents will be detrimental when it comes to toxicity, flammability and waste iteration. for that reason, substitute solvents now shape a considerable a part of eco-friendly chemistry. This e-book covers the newest advancements during this becoming box in addition to a few key components which have been missed in prior literature. Solvents are very important in lots of components of chemistry so the writer has followed a basic process encompassing of a variety of solvents. As a part of the golf green Chemistry sequence, examples are used that tie in with the 12 ideas of eco-friendly chemistry equivalent to atom effective reactions in benign solvents, processing of renewable chemical compounds and fabrics in eco-friendly solvents.

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Additional info for Alternative Solvents for Green Chemistry (RSC Green Chemistry Series)

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Anastas and J. C. Warner, Green Chemistry: Theory and Practice, Oxford University Press, New York, 1998. 2. J. H. Clark and D. J. Macquarrie, Handbook of Green Chemistry and Technology, Blackwell Science, London, 2002. 3. M. Lancaster, Green Chemistry: An Introductory Text, Royal Society of Chemistry, Cambridge, UK, 2002. 4. D. J. Adams, P. J. Dyson and S. J. Taverner, Chemistry in Alternative Reaction Media, John Wiley & Sons Ltd, Chichester, 2004. 5. K. Mikami, in Green Reaction Media in Organic Synthesis, Wiley-Blackwell, Oxford, 2005.

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6) [Bmim][PF6] 98 50 40 10 2 o1 35 Base catalysed Baylis–Hillman reaction under solvent free conditions and using an HSBM. were used to purify the product by column chromatography. Therefore, although reduced in solvent demand this reaction is not entirely solvent free. 25 This reaction affords useful multifunctional products from an addition reaction between an electrophile (often an aldehyde) and an electron-deficient olefin. Unfortunately, under most conditions it has the significant drawback of a slow rate of reaction.

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